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Catalytic Converters

Catalytic converters can either be an oxidation or three-way type. Oxidation catalysts convert carbon monoxide (CO) and hydrocarbons (HC) to carbon dioxide (CO2) and water, but have little effect on nitrogen oxides (NOx) and particulate matter. Three-way catalysts operate in a closed-loop system together with a lambda, or oxygen, sensor to regulate the air/fuel ratio on gasoline engines. The catalyst can then at the same time oxidize CO and HC to CO2 and water while reducing NOx to nitrogen.

Most cars today are equipped with a three-way catalytic converter. The term Three-way refers to the three emissions it helps to reduce, carbon monoxide, hydrocarbons or volatile organic compounds (VOCs) and NOx molecules. The converter uses two different types of catalysts, a reduction catalyst and an oxidization catalyst. Both types consist of a base structure coated with a catalyst such as platinum, rhodium and/or palladium. The scheme is to create a structure that exposes the maximum surface area of the catalyst to the exhaust flow, while also minimizing the amount of catalyst required.

The inside of the catalytic converter is a honeycomb set of passageways or small ceramic beads coated with catalysts. A chemical reaction takes place to make the pollutants less harmful. There are many passages for the exhaust gases to flow, to allow for the maximum amount of surface area for the hot gases to pass.

In order to reduce emissions, modern car engines carefully control the amount of fuel they burn. They try to keep the air-to-fuel ratio very close to the stoichiometric point, which is the calculated ideal ratio of air to fuel. Theoretically, at this ratio, all of the fuel will be burned using all of the oxygen in the air. For gasoline engines the stoichiometric ratio is about 14.7:1. This means that for every pound of gasoline, 14.7 pounds of air will be burned. As engine and driving conditions change, this ratio changes as well. Sometimes it will run richer or leaner than the ideal 14.7:1. 

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